Synthesis, characterization, and reactivity of a side-on manganese(III)–peroxo complex bearing a pentadentate aminopyridine ligand----Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences

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Synthesis, characterization, and reactivity of a side-on manganese(III)–peroxo complex bearing a pentadentate aminopyridine ligand

2016-07-15

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Abstract: A manganese(II) complex has been prepared with a proline-derived pentadentate ligand (Pro3Py), and it can be converted to a peroxo-manganese(III) complex in the presence of H₂O₂ and triethylamine. The resulting peroxomanganese(III) complex was well characterised by UV-vis, EPR and ESI-MS techniques, and the geometric structure was discussed based on DFT calculations.

KeyWords Plus: MANGANESE SUPEROXIDE-DISMUTASE; C-H; ELECTRONIC-STRUCTURES; LOW-TEMPERATURE; ENANTIOSELECTIVE EPOXIDATION; BOND-CLEAVAGE; MN-II; H2O2; OXIDATION; PEROXO

Published in DALTON TRANSACTIONS, 45 (25):10131-10135; 10.1039/c6dt00508j 2016