An efficient approach toward formation of polycyclic coumarin derivatives via carbocation-initiated [4+2] cycloaddition and atom-economical photo-irradiated cyclization----Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences

Research

Location: Home>Research>Research Progress

An efficient approach toward formation of polycyclic coumarin derivatives via carbocation-initiated [4+2] cycloaddition and atom-economical photo-irradiated cyclization

2016-11-19

ArticleSource:

Text Size: A A A

Abstract: Facile carbocation-initiated [4+2] cycloaddition of o-anisole-substituted propargyl silyl ethers and ynamides led to the formation of 4-vinylcoumarins. Subsequent intramolecular cyclization of 3-aryl-4-vinylcoumarins afforded polycyclic coumarin derivatives 11,12-dihydronaphtho[1,2-c] chromen-5-ones in excellent yields under mild photo-irradiated conditions established by fluorescence analysis-oriented screening.

KeyWords Plus:PROPARGYLIC ALCOHOLS; FLUORESCENT-PROBES; SILYL ETHERS; YNAMIDES; ACID; REARRANGEMENTS; ALDEHYDES; CATALYST

Published in CHEMICAL COMMUNICATIONS, 52 (74):11131-11134; 10.1039/c6cc05698a 2016