ZHANG Yan1,2,3, WANG Lailai1*
(1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Lanzhou 730000, China; 2. Graduate University of the Chinese Academy of Sciences, Beijing 100049, China; 3. School of Traffic and Transportation, Lanzhou Jiaotong University, Lanzhou 730070, China)
Abstract: In this papers, we will summarize the past decade, synthesis of phosphite ligands and their application in asymmetric hydrogenation. Were introduced design and synthesis of bidentate, monodentate, and heterocyclic P, P 'ligands, heterocyclic P, N ligands, as well as in catalytic asymmetric hydrogenation of the results obtained and briefly discussed aspects of the mechanism. For each specific reaction, we are particularly concerned about the optimization of reaction conditions.
Key words: Chiral; phosphite ligands; asymmetric hydrogenation
E-mail: refuser@163.com
Journal of Molecular Catalysis, Vol. 25, Issue 5, 2011, 449-466
