Abstract
A novel porous organic polymer catalyst with in situ encapsulated single-site Rh (Rh@CPOL-DPMphos&p-3vPPh(3)) was developed and employed in heterogeneous hydroaminomethylation of alkenes, affording the corresponding amines in good to excellent regioselectivity and catalytic activity by a one-pot method. The combined actions of hierarchical pore confinement and the biphosphine ligand derived from the POP catalyst contributed to the improved regioselectivity.

Keywords Plus：POROUS ORGANIC POLYMERSHYDROFORMYLATIONEFFICIENTRHODIUMAMINES

Published in CHEMICAL COMMUNICATIONS，Volume58；10.1039/d2cc02469a，JUL 19 2022