Abstract: The electron spin properties of a fulleropyrrolidine nitroxide radical incarcerated in the pores of MOF-177 and MIL-53 respectively were investigated for the first time. It was found that the spatial confinement effect and intramolecular interactions in these two solid-state spin systems lead to dramatically distinctive spin dynamics.

KeyWords Plus:ENDOHEDRAL METALLOFULLERENES; SOLID-STATE; EPR; FULLERENE; COMPLEXATION; RESONANCE; TEMPERATURE; CLUSTER; SPECTROSCOPY; DERIVATIVES

Published in DALTON TRANSACTIONS, 45 (28):11272-11276; 10.1039/c6dt01735e 2016